Cu Ii Catalyzed Functionalizations Of Aryl Cв H Bonds Using O2 As An

Cu Ii Catalyzed Functionalizations Of Aryl Cв H Bonds U Cu(ii) catalyzed acetoxylation and halogenation of aryl c−h bonds are developed. ortho selectivity was observed with a wide range of 2 arylpyridine substrates. both mono and difunctionalizations are achieved by tuning the reaction conditions. excellent functional group tolerance and use of o2 as a stoichiometric oxidant are significant advantages over our recently developed pd catalyzed c. These newly discovered reaction conditions are also applicable for cyanation, amination, etherification, and thioetherification of aryl c h bonds. cu(ii) catalyzed acetoxylation and halogenation of aryl c h bonds are developed. ortho selectivity was observed with a wide range of 2 arylpyridine substrates. both mono and difunctionalizations are achieved by tuning the reaction conditions.

A Schematic Representation Of The Work Rationale Assessing The Cu(ii) catalyzed functionalizations of aryl c—h bonds using o 2 as an oxidant. xiao chen, xiao chen. dep. chem., brandeis univ., waltham, ma 02454, usa. Cu(ii)‐catalyzed functionalizations of aryl c—h bonds using o2 as an oxidant. @article{chen2006cuiicatalyzedfo, title={cu(ii)‐catalyzed functionalizations of aryl c—h bonds using o2 as an oxidant.}, author={xiao chen and xue shi hao and charles e. goodhue and jin quan yu}, journal={cheminform}, year={2006}, volume={37}, url={ api. Cu(ii) catalyzed functionalizations of aryl c h bonds using o2 as an oxidant. sign in | create an account. orcid.org. europe pmc. menu. about. about europe. Cu (ii) catalyzed acetoxylation and halogenation of aryl c h bonds are developed. ortho selectivity was observed with a wide range of 2 arylpyridine substrates. both mono and difunctionalizations.

Table 1 From Ni Cu Catalyzed Defluoroborylation Of Fluoroarenes For Cu(ii) catalyzed functionalizations of aryl c h bonds using o2 as an oxidant. sign in | create an account. orcid.org. europe pmc. menu. about. about europe. Cu (ii) catalyzed acetoxylation and halogenation of aryl c h bonds are developed. ortho selectivity was observed with a wide range of 2 arylpyridine substrates. both mono and difunctionalizations. Cu(ii) catalyzed functionalizations of aryl c−h bonds using o2 as an oxidant (pdf) cu(ii) catalyzed functionalizations of aryl c−h bonds using o2 as an oxidant | charles goodhue academia.edu academia.edu no longer supports internet explorer. Key takeaway: 'cu(ii) catalyzed functionalizations of aryl c h bonds using o2 as an oxidant offer excellent functional group tolerance and stoichiometric oxidant advantages over pd catalyzed c h functionalization reactions.'.